Charge Carried by Electrons and Protons

Franklin wrote in his letters and books that he could see the effects of electric charge but did not understand what caused the phenomenon. Today we have the advantage of knowing that normal matter is made of atoms, and that atoms contain positive and negative charges, usually in equal amounts.

[link] shows a simple model of an atom with negative electrons orbiting its positive nucleus. The nucleus is positive due to the presence of positively charged protons. Nearly all charge in nature is due to electrons and protons, which are two of the three building blocks of most matter. (The third is the neutron, which is neutral, carrying no charge.) Other charge-carrying particles are observed in cosmic rays and nuclear decay, and are created in particle accelerators. All but the electron and proton survive only a short time and are quite rare by comparison.

The charges of electrons and protons are identical in magnitude but opposite in sign. Furthermore, all charged objects in nature are integral multiples of this basic quantity of charge, meaning that all charges are made of combinations of a basic unit of charge. Usually, charges are formed by combinations of electrons and protons. The magnitude of this basic charge is

The symbol $q$ is commonly used for charge and the subscript $e$ indicates the charge of a single electron (or proton).

The SI unit of charge is the coulomb (C). The number of protons needed to make a charge of 1.00 C is

Similarly, $6\text{.}\text{25}\times {\text{10}}^{\text{18}}$ electrons have a combined charge of −1.00 coulomb. Just as there is a smallest bit of an element (an atom), there is a smallest bit of charge. There is no directly observed charge smaller than $\mid q_e\mid$ (see Things Great and Small: The Submicroscopic Origin of Charge), and all observed charges are integral multiples of $\mid q_e\mid$.

[link] shows a person touching a Van de Graaff generator and receiving excess positive charge. The expanded view of a hair shows the existence of both types of charges but an excess of positive. The repulsion of these positive like charges causes the strands of hair to repel other strands of hair and to stand up. The further blowup shows an artist’s conception of an electron and a proton perhaps found in an atom in a strand of hair.

The electron seems to have no substructure; in contrast, when the substructure of protons is explored by scattering extremely energetic electrons from them, it appears that there are point-like particles inside the proton. These sub-particles, named quarks, have never been directly observed, but they are believed to carry fractional charges as seen in [link]. Charges on electrons and protons and all other directly observable particles are unitary, but these quark substructures carry charges of either $-\frac{1}{3}$ or $+\frac{2}{3}$. There are continuing attempts to observe fractional charge directly and to learn of the properties of quarks, which are perhaps the ultimate substructure of matter.

Separation of Charge in Atoms

Charges in atoms and molecules can be separated—for example, by rubbing materials together. Some atoms and molecules have a greater affinity for electrons than others and will become negatively charged by close contact in rubbing, leaving the other material positively charged. (See [link].) Positive charge can similarly be induced by rubbing. Methods other than rubbing can also separate charges. Batteries, for example, use combinations of substances that interact in such a way as to separate charges. Chemical interactions may transfer negative charge from one substance to the other, making one battery terminal negative and leaving the first one positive.

No charge is actually created or destroyed when charges are separated as we have been discussing. Rather, existing charges are moved about. In fact, in all situations the total amount of charge is always constant. This universally obeyed law of nature is called the law of conservation of charge.

In more exotic situations, such as in particle accelerators, mass, $\mathrm{\Delta }m$, can be created from energy in the amount $\mathrm{\Delta }m=\frac{E}{c^2}$. Sometimes, the created mass is charged, such as when an electron is created. Whenever a charged particle is created, another having an opposite charge is always created along with it, so that the total charge created is zero. Usually, the two particles are “matter-antimatter” counterparts. For example, an antielectron would usually be created at the same time as an electron. The antielectron has a positive charge (it is called a positron), and so the total charge created is zero. (See [link].) All particles have antimatter counterparts with opposite signs. When matter and antimatter counterparts are brought together, they completely annihilate one another. By annihilate, we mean that the mass of the two particles is converted to energy E, again obeying the relationship $\mathrm{\Delta }m=\frac{E}{c^2}$. Since the two particles have equal and opposite charge, the total charge is zero before and after the annihilation; thus, total charge is conserved.

The law of conservation of charge is absolute—it has never been observed to be violated. Charge, then, is a special physical quantity, joining a very short list of other quantities in nature that are always conserved. Other conserved quantities include energy, momentum, and angular momentum.